The innovation engine for new materials

Kathryn Hasz

Kathryn Hasz

Major: 

Physics

University: 

Oberlin College

Mentor(s): 

Jakoah Brgoch

Faculty Sponsor(s): 

Ram Seshadri

Faculty Sponsor's Department(s): 

Materials

Project Title: 

EUROPIUM-SUBSTITUTED PHOSPHORS FOR SOLID STATE WHITE LIGHTING

Project Description: 

Europium-substituted compounds of Ba1-xY2-yEux+ySi3O10 and Ba1-xLux-yEux+ySi3O10 have been prepared as 1 efficient green phosphors fur use in solid state white lighting.  The compounds were prepared using a high-temperature solid state route and characterized by powder X-ray diffraction and flourescence spectroscopy.  Photoluminescent characterization identified a broad excitation peak ranging from <250 nm to 400 nm (UV to deep blue) and a broad emission across nearly the entire visible region that varied depending on Eu2+ concentration.  The emissions cover from about 400 nm to >600 nm, producing a greenish-white light.  The optimized quantum yield for both compounds is approximately 30% with an optimized Eu2+ concentration of 3% and 1% respectively, which is comparable with other broad emission phosphors.