The innovation engine for new materials

Andrew Oh

Andrew Oh

Major: 

Materials Science and Engineering

University: 

Rutgers University

Mentor(s): 

Eric Rind

Faculty Sponsor(s): 

James S. Speck

Faculty Sponsor's Department(s): 

Materials

Project Title: 

HIGH QUALITY EPITAXIAL GROWTH OF In¬2O3 THIN FILMS ON YSZ: EXISTENCE OF EPITAXY BOUNDARIES

Project Description: 

In recent years In2O3 has garnered much attention within the transparent semiconducting oxide community because of its applications in photovoltaics and opto-electronic devices. It has been in the shadows of its doped form, tin-doped indium oxide, since its discovery, thus, detailed characterizations have not been done. In our work, we investigate the intrinsic electronic properties of In2O3, mainly focusing on increasing the electron mobility within the bulk. Using plasma-assisted molecular beam epitaxy (PA-MBE), In­2O3 was grown on yttrium-stabilized zirconia (YSZ). While examining the visual data collected from AFM, TEM, and STEM we observed defects develop at island coalescence boundaries. Cross-sectional TEM images of In­2O3 thin films revealed these defects promoted threading dislocations along its length. Upon close inspection of indium atoms within the samples using STEM, a shifting of differently ordered indium rows confirmed the presence of antiphase boundaries (APBs). APBs are associated with like-like atomic bonding creating inconsistencies within the lattice which highly restrict electron mobility. As a result, few nucleation sites are sought to reduce the chances of APB formation and to have greater electron mobility. Previous works suggest that growing in an In-rich environment and relatively high temperatures of about 680oC will produce an In2O3 film with the least amount of APBs and consequently the highest electron mobility.